SAFT NiCd "block" battery high cell voltage

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SAFT NiCd "block" battery high cell voltage Bob F 01-29-2008
Posted by Bob F on January 29, 2008, 6:56 pm
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Any experts here on large nicads?

I just picked up 45 used SAFT SBM43-2 NiCd "block" batteries. Each battery
appears to be 2- 43 AH cells with a jumper bar attached between the two cells
putting them in series electrically. Each battery measures 3.4-3.62 volts, which
seems on the high side for 2 cells voltage. According to the technical manual,
they should be charged at 1.7V/cell max, which would produce 3.4V / battery.
Could the higher voltage be indicative of batteries near their life end? Or were
they last charged at too high of a voltage? Or??

Cost - 20 mile drive each way.

http://www.saftbatteries.com//130-Catalogue/PDF/tm_bb_en.pdf
http://www.saftbatteries.com//130-Catalogue/PDF/com-data_bb_en.pdf



Posted by Neon John on January 29, 2008, 9:00 pm
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>Any experts here on large nicads?

Don't know about expert but somewhat experienced.
>
>I just picked up 45 used SAFT SBM43-2 NiCd "block" batteries. Each battery
>appears to be 2- 43 AH cells with a jumper bar attached between the two cells
>putting them in series electrically. Each battery measures 3.4-3.62 volts,
which
>seems on the high side for 2 cells voltage. According to the technical manual,
>they should be charged at 1.7V/cell max, which would produce 3.4V / battery.
>Could the higher voltage be indicative of batteries near their life end? Or
were
>they last charged at too high of a voltage? Or??

Wet NiCads are almost impossible to kill and their lives are measured in
half-centuries. My oldest wet battery is a Korean-war-vintage 28 volt aircraft
starter battery. Still at full rated capacity. I've had to change the
electrolyte
(KOH) a couple of times, as CO2 from the air slowly neutralizes it, but other
than
that and an occasional watering, nothing else done.

You can't hurt a wet NiCad with moderate over-charging or discharging. In fact,
the
usual storage configuration for wet cells is fully discharged and shorted. All
they
do on over-charge is get warm and use more water. The plates will NOT lose
active
material like PbAs do. Moderate over-charge of a series string is necessary for
proper equalization. I suggest putting some cells through charge/discharge
cycles
and see what you get.

I think that SAFT adds something to their electrolyte that raises the voltage a
tiny
bit. That may be the root of what you're seeing. You might drop SAFT a note and
ask. SAFT says not to change the electrolyte but that may be necessary if these
cells were not stored properly. Again, they can tell you for sure.
>
>Cost - 20 mile drive each way.

I'm green with envy :-)

John
--
John De Armond
See my website for my current email address
http://www.neon-john.com
http://www.johndearmond.com <-- best little blog on the net!
Tellico Plains, Occupied TN
Better remain silent and be thought a fool than to cite Wikipedia and remove all
doubt.


Posted by Solar Flare on January 29, 2008, 9:03 pm
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I maintained a few ni-cad banks years ago. 1.22, 1.33 & 1.44 volts per
cell rings a bell. I think that was nominal, float and equalize
voltages.

You really need a constant current charger as the voltage is a really
nonlinear curve to their charge.
Things I remember
- we used them in outside stations as their cold curve was much better
- they had small capacity per size compared to lead/acid units
- we got rid of them all
- chargers like to "hunt" or oscillate if you try to charge them with
a voltage unit. Touching feedback damping was the key to prevent it.
Most chargers these days have never heard of this adjustment

Have fun.


> Any experts here on large nicads?
>
> I just picked up 45 used SAFT SBM43-2 NiCd "block" batteries. Each
> battery appears to be 2- 43 AH cells with a jumper bar attached
> between the two cells putting them in series electrically. Each
> battery measures 3.4-3.62 volts, which seems on the high side for 2
> cells voltage. According to the technical manual, they should be
> charged at 1.7V/cell max, which would produce 3.4V / battery. Could
> the higher voltage be indicative of batteries near their life end?
> Or were they last charged at too high of a voltage? Or??
>
> Cost - 20 mile drive each way.
>
> http://www.saftbatteries.com//130-Catalogue/PDF/tm_bb_en.pdf
> http://www.saftbatteries.com//130-Catalogue/PDF/com-data_bb_en.pdf
>



Posted by Bob F on February 4, 2008, 8:53 pm
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> Any experts here on large nicads?
>
> I just picked up 45 used SAFT SBM43-2 NiCd "block" batteries. Each battery
> appears to be 2- 43 AH cells with a jumper bar attached between the two cells
> putting them in series electrically. Each battery measures 3.4-3.62 volts,
> which seems on the high side for 2 cells voltage. According to the technical
> manual, they should be charged at 1.7V/cell max, which would produce 3.4V /
> battery. Could the higher voltage be indicative of batteries near their life
> end? Or were they last charged at too high of a voltage? Or??
>
> Cost - 20 mile drive each way.
>
> http://www.saftbatteries.com//130-Catalogue/PDF/tm_bb_en.pdf
> http://www.saftbatteries.com//130-Catalogue/PDF/com-data_bb_en.pdf
>

Thank you both for the info.

Bob F



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