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NEWS: Stanford's nanowire battery holds 10 times the charge of existing ones

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Posted by jim on January 4, 2008, 9:14 am
 
(from
http://news-service.stanford.edu/news/2008/january9/nanowire-010908.html )

Stanford Report, December 18, 2007
Stanford's nanowire battery holds 10 times the charge of existing ones

BY DAN STOBER


Stanford researchers have found a way to use silicon nanowires to reinvent
the rechargeable lithium-ion batteries that power laptops, iPods, video
cameras, cell phones, and countless other devices.

The new version, developed through research led by Yi Cui, assistant
professor of materials science and engineering, produces 10 times the amount
of electricity of existing lithium-ion, known as Li-ion, batteries. A laptop
that now runs on battery for two hours could operate for 20 hours, a boon to
ocean-hopping business travelers.

"It's not a small improvement," Cui said. "It's a revolutionary
development."

The breakthrough is described in a paper, "High-performance lithium battery
anodes using silicon nanowires," published online Dec. 16 in Nature
Nanotechnology, written by Cui, his graduate chemistry student Candace Chan
and five others.

The greatly expanded storage capacity could make Li-ion batteries attractive
to electric car manufacturers. Cui suggested that they could also be used in
homes or offices to store electricity generated by rooftop solar panels.

"Given the mature infrastructure behind silicon, this new technology can be
pushed to real life quickly," Cui said.

The electrical storage capacity of a Li-ion battery is limited by how much
lithium can be held in the battery's anode, which is typically made of
carbon. Silicon has a much higher capacity than carbon, but also has a
drawback.

Silicon placed in a battery swells as it absorbs positively charged lithium
atoms during charging, then shrinks during use (i.e., when playing your
iPod) as the lithium is drawn out of the silicon. This expand/shrink cycle
typically causes the silicon (often in the form of particles or a thin film)
to pulverize, degrading the performance of the battery.

Cui's battery gets around this problem with nanotechnology. The lithium is
stored in a forest of tiny silicon nanowires, each with a diameter
one-thousandth the thickness of a sheet of paper. The nanowires inflate four
times their normal size as they soak up lithium. But, unlike other silicon
shapes, they do not fracture.

Research on silicon in batteries began three decades ago. Chan explained:
"The people kind of gave up on it because the capacity wasn't high enough
and the cycle life wasn't good enough. And it was just because of the shape
they were using. It was just too big, and they couldn't undergo the volume
changes."

Then, along came silicon nanowires. "We just kind of put them together,"
Chan said.

For their experiments, Chan grew the nanowires on a stainless steel
substrate, providing an excellent electrical connection. "It was a fantastic
moment when Candace told me it was working," Cui said.

Cui said that a patent application has been filed. He is considering
formation of a company or an agreement with a battery manufacturer.
Manufacturing the nanowire batteries would require "one or two different
steps, but the process can certainly be scaled up," he added. "It's a well
understood process."

Also contributing to the paper in Nature Nanotechnology were Halin Peng and
Robert A. Huggins of Materials Science and Engineering at Stanford, Gao Liu
of Lawrence Berkeley National Laboratory, and Kevin McIlwrath and Xiao Feng
Zhang of the electron microscope division of Hitachi High Technologies in
Pleasanton, Calif



Posted by jim on January 4, 2008, 9:54 am
 


You do realize that that means that a Tesla raodster could go up to 2500
miles on a single charge!

Wow!

Now maybe we can do something about automobile pollution, at least.

I know all about the percentages of pollution so don't get your geek in a
wad.  But reducing (or eliminating) auto exhaust will definitely improve
local air quality and may even help cool cities off a couple of degrees in
the summer.  Not to mention the new quiet engines.....

jim



Posted by Eeyore on January 4, 2008, 1:02 pm
 

jim wrote:


This means more people will get run over.

Graham


Posted by RadicalModerate on January 4, 2008, 2:04 pm
 I plan on buying two generators this year.

One stationary generator to power the house...using gasoline/diesel
and natural gas.

The other as a portable generator using gasoline.

I understand the need to size the generators for the respective loads
they will support.

What generators would you recommend and where to buy them?

Thanks

TMT

Posted by Alex on January 4, 2008, 3:24 pm
 On 4 Jan, 19:04, radicalmoder...@attnn.com (RadicalModerate) wrote:

Not really. There's plenty of free capacity at night time.

Vehicle to Grid could actually reduce the amount of generation
capacity required, especially if wind energy is widely deployed.


To some extent. EVs running on coal would provide a win compared to
inefficient petrol engines, but no compared to a high efficiency
diesel. Local pollution is of course greatly reduced and coal power
stations at least have the the potential for carbon capture.


So is very wide scale deployment of electric cars. And I still can't
figure out why Wm Mook is trying to make hydrogen when he could just
stop at electricity.

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